Análise de NO2, NH3 e PTS na Atmosfera de Paranaguá - PR

Autores

DOI:

https://doi.org/10.21664/2238-8869.2020v9i1.p212-229

Palavras-chave:

Poluição Atmosférica, Porto, Paranaguá

Resumo

As áreas portuárias são centros de atividades econômicas e também grandes geradoras de impactos ao meio ambiente. Nestas, ocorrem várias fontes de emissão de poluentes para a atmosfera. As consequências na saúde da população local, devido à grande emissão de poluentes no ar são diversas, e consistem no maior risco ambiental a saúde humana atualmente. Paranaguá tem sua economia baseada na atividade portuária, sendo o porto de Paranaguá um dos mais importantes do Brasil e o maior exportador de grãos da América Latina. Neste estudo, foi utilizado um equipamento chamado de APV (Amostrador de Pequeno Volume) para avaliação das concentrações de amônia (NH3) e dióxido de nitrogênio (NO2) e um AGV (Amostrador de Grande volume) para a avaliação de material particulado em suspensão (PTS). O monitoramento da qualidade do ar foi realizado ao longo de 12 meses. A média anual para dióxido de nitrogênio, amônia e Partículas totais em suspensão ficou no entorno de 12,9 ± 7,41 µg/m3, 3,61 ± 3,82 µg/m3 e 73,91 μg/m³ ± 36,71 μg/m³ respectivamente. Os dados foram relacionados com variáveis climática e de tráfego rodoviário, utilizando-se para isto o software estatístico R. As médias anuais dos poluentes amostrados foram comparadas aos resultados obtidos em pesquisas ao redor do mundo, identificando valores similares ou superiores aos de localidades mais populosas ou com intensas atividades antrópicas.

Biografia do Autor

Felipe Foroni Cota Souza, Universidade Federal do Paraná, UFPR, Brasil.

Mestrado em Desenvolvimento Territorial Sustentável pela Universidade Federal do Paraná, UFPR, Brasil.

Edipo Vinicius Tagliatela, Universidade Federal do Paraná, UFPR, Brasil.

Mestrado em Desenvolvimento Territorial Sustentável pela Universidade Federal do Paraná, UFPR, Brasil.

Bruno Martins Gurgatz, Universidade Federal do Paraná, UFPR, Brasil.

Doutorado em andamento em Sistemas Costeiros e Oceânicos pela Universidade Federal do Paraná, UFPR, Brasil. Mestrado em Desenvolvimento Territorial Sustentável pela Universidade Federal do Paraná, UFPR, Brasil.

Luciano Fernandes Huergo, Universidade Federal do Paraná, UFPR, Brasil. 

Doutorado em Ciências (Bioquímica) pela Universidade Federal do Paraná, UFPR, Brasil; com período sanduíche em John Innes Centre. Docente na Universidade Federal do Paraná, UFPR, Brasil. 

Rodrigo Arantes Reis, Universidade Federal do Paraná, UFPR, Brasil. 

Doutorado em Ciências (Bioquímica) pela Universidade Federal do Paraná, UFPR, Brasil; com período sanduíche em Karl-Franzens-University Graz. Docente na Universidade Federal do Paraná, UFPR, Brasil. 

Referências

Aardenne, J. A. van, F. J. Dentener, J. G. J. Olivier, C. G. M. Klein Goldewijk, and J. Lelieveld. 2001. “A 1°×1° Resolution Data Set of Historical Anthropogenic Trace Gas Emissions for the Period 1890-1990.” Global Biogeochemical Cycles 15 (4): 909–28. https://doi.org/10.1029/2000GB001265.
Alebic-Juretic, Ana. 2008. “Airborne Ammonia and Ammonium within the Northern Adriatic Area, Croatia.” Environmental Pollution 154 (3): 439–47. https://doi.org/10.1016/j.envpol.2007.11.029.
Anatolaki, Ch., and R. Tsitouridou. 2007. “Atmospheric Deposition of Nitrogen, Sulfur and Chloride in Thessaloniki, Greece.” Atmospheric Research 85 (3–4): 413–28. https://doi.org/10.1016/j.atmosres.2007.02.010.
Backes, Anna M., Armin Aulinger, Johannes Bieser, Volker Matthias, and Markus Quante. 2016. “Ammonia Emissions in Europe, Part II: How Ammonia Emission Abatement Strategies Affect Secondary Aerosols.” Atmospheric Environment 126 (February): 153–61. https://doi.org/10.1016/j.atmosenv.2015.11.039.
Bari, Abdul, Vincent Ferraro, Lloyd R. Wilson, Dan Luttinger, and Liaquat Husain. 2003. “Measurements of Gaseous HONO, HNO3, SO2, HCl, NH3, Particulate Sulfate and PM2.5 in New York, NY.” Atmospheric Environment 37 (20): 2825–35. https://doi.org/10.1016/S1352-2310(03)00199-7.
Basahi, J. M., I. M. Ismail, and I. A. Hassan. 2014. “A Global Challenge of Air Pollution and Public Health: A Mini Review.” Advances in Environmental Biology 8 (21): 281–88.
Behera, Sailesh N., and Mukesh Sharma. 2010. “Investigating the Potential Role of Ammonia in Ion Chemistry of Fine Particulate Matter Formation for an Urban Environment.” Science of The Total Environment 408 (17): 3569–75. https://doi.org/10.1016/j.scitotenv.2010.04.017.
Braga, Alfesio, Luiz Alberto Amador Pereira, György Miklós Böhm, and Paulo Saldiva. 2001. “Poluição Atmosférica e Saúde Humana.” Revista USP, no. 51 (November): 58. https://doi.org/10.11606/issn.2316-9036.v0i51p58-71.
Cai, Xianlei, Zhenhong Li, E. Marian Scott, Xiuyang Li, and Mengyao Tang. 2016. “Short-Term Effects of Atmospheric Particulate Matter on Myocardial Infarction: A Cumulative Meta-Analysis.” Environmental Science and Pollution Research 23 (7): 6139–48. https://doi.org/10.1007/s11356-016-6186-3.
Carmichael, Gregory R, Martin Ferm, Narisara Thongboonchoo, Jung-Hun Woo, L.Y Chan, Kentaro Murano, Pham Hung Viet, et al. 2003. “Measurements of Sulfur Dioxide, Ozone and Ammonia Concentrations in Asia, Africa, and South America Using Passive Samplers.” Atmospheric Environment 37 (9–10): 1293–1308. https://doi.org/10.1016/S1352-2310(02)01009-9.
Carslaw, David C., and Karl Ropkins. 2012. “Openair — An R Package for Air Quality Data Analysis.” Environmental Modelling & Software 27–28 (January): 52–61. https://doi.org/10.1016/j.envsoft.2011.09.008.
Chiwa, Masaaki. 2010. “Characteristics of Atmospheric Nitrogen and Sulfur Containing Compounds in an Inland Suburban-Forested Site in Northern Kyushu, Western Japan.” Atmospheric Research 96 (4): 531–43. https://doi.org/10.1016/j.atmosres.2010.01.001.
CONAMA. 2018. Resolução n. 491, de 19 de Novembro de 2018. Dispõe Sobre Padrões de Qualidade Do Ar. Brasília: Ministério do Meio Ambiente; Conselho Nacional do Meio Ambiente. http://www.in.gov.br/materia/-/asset_publisher/Kujrw0TZC2Mb/content/id/51058895.
Day, D.E., X. Chen, K.A. Gebhart, C.M. Carrico, F.M. Schwandner, K.B. Benedict, B.A. Schichtel, and J.L. Collett. 2012. “Spatial and Temporal Variability of Ammonia and Other Inorganic Aerosol Species.” Atmospheric Environment 61 (December): 490–98. https://doi.org/10.1016/j.atmosenv.2012.06.045.
Energética Ltda. 2016. “Método Para Determinação de Dióxido de Nitrogênio Na Atmosfera Com Arsenito de Sódio, Equivalente a US EPA – No EQN – 1277-026.” http://www.energetica.ind.br/wp/env1/wpcontent/uploads/2016/01/env1_metodo-epa-no2-arsenito-sodio-eqn-277-026-rev01.pdf.
Foroni, Felipe, Bruno Martins Gurgatz, Édipo Tagliatela, and Rodrigo Arantes Reis. 2017. “Poluição Atmosférica, Atividade Portuária e Industrial Em Paranaguá, Paraná: Um Estudo Sobre Contaminação Por Amônia (NH3) e Dióxido de Nitrogênio (NO2).” In Anais Do II Simpósio Brasileiro de Desenvolvimento Territorial Sustentável, 1337–46. Matinhos: Universidade Federal do Paraná.
Fountoukis, C., A. Nenes, A. Sullivan, R. Weber, T. Van Reken, M. Fischer, E. Matías, M. Moya, D. Farmer, and R. C. Cohen. 2009. “Thermodynamic Characterization of Mexico City Aerosol during MILAGRO 2006.” Atmospheric Chemistry and Physics 9 (6): 2141–56. https://doi.org/10.5194/acp-9-2141-2009.
Francová, Anna, Vladislav Chrastný, Hana Šillerová, Martina Vítková, Jana Kocourková, and Michael Komárek. 2017. “Evaluating the Suitability of Different Environmental Samples for Tracing Atmospheric Pollution in Industrial Areas.” Environmental Pollution 220 (January): 286–97. https://doi.org/10.1016/j.envpol.2016.09.062.
Guerriero, Carla, Lia Chatzidiakou, John Cairns, and Dejan Mumovic. 2016. “The Economic Benefits of Reducing the Levels of Nitrogen Dioxide (NO2) near Primary Schools: The Case of London.” Journal of Environmental Management 181 (October): 615–22. https://doi.org/10.1016/j.jenvman.2016.06.039.
Gupta, A.K., Kakoli Karar, S. Ayoob, and Kuruvilla John. 2008. “Spatio-Temporal Characteristics of Gaseous and Particulate Pollutants in an Urban Region of Kolkata, India.” Atmospheric Research 87 (2): 103–15. https://doi.org/10.1016/j.atmosres.2007.07.008.
Habeš, Suad, Zarema Obradović, Aida Ridžal, and Asmir Aldžić. 2013. “Air Pollution by Nitrogen Oxides in Sarajevo from 2005 to 2010.” Journal of Health Sciences 3 (3): 250–54. https://doi.org/10.17532/jhsci.2013.116.
Hassan, Salwa K., Ahmed A. El–Abssawy, and Mamdouh I. Khoder. 2013. “Characteristics of Gas–Phase Nitric Acid and Ammonium–Nitrate– Sulfate Aerosol, and Their Gas–Phase Precursors in a Suburban Area in Cairo, Egypt.” Atmospheric Pollution Research 4 (1): 117–29. https://doi.org/10.5094/APR.2013.012.
Ianniello, A., F. Spataro, G. Esposito, I. Allegrini, E. Rantica, M. P. Ancora, M. Hu, and T. Zhu. 2010. “Occurrence of Gas Phase Ammonia in the Area of Beijing (China).” Atmospheric Chemistry and Physics 10 (19): 9487–9503. https://doi.org/10.5194/acp-10-9487-2010.
IBGE. 2019. “População Estimada Do Município de Paranaguá-PR No Ano de 2019.” IBGE (Instituto Brasileiro de Geografia e Estatística). 2019. https://cidades.ibge.gov.br/brasil/pr/paranagua/panorama.
Ilyas, SZ. 2010. “A Review of Transport and Urban Air Pollution in Pakistan.” Journal of Applied Sciences and Environmental Management 11 (2): 113–121. https://doi.org/10.4314/jasem.v11i2.55004.
Khwaja, Mahmood A., and Shaheen Rafi Khan. 2005. “Air Pollution: Key Environmental Issues in Pakistan.”
Krupa, S.V. 2003. “Effects of Atmospheric Ammonia (NH3) on Terrestrial Vegetation: A Review.” Environmental Pollution 124 (2): 179–221. https://doi.org/10.1016/S0269-7491(02)00434-7.
Li, Huiming, Xin Qian, and Qin’geng Wang. 2013. “Heavy Metals in Atmospheric Particulate Matter: A Comprehensive Understanding Is Needed for Monitoring and Risk Mitigation.” Environmental Science & Technology 47 (23): 13210–11. https://doi.org/10.1021/es404751a.
Lin, Hualiang, Jun Tao, Yaodong Du, Tao Liu, Zhengmin Qian, Linwei Tian, Qian Di, et al. 2016. “Particle Size and Chemical Constituents of Ambient Particulate Pollution Associated with Cardiovascular Mortality in Guangzhou, China.” Environmental Pollution 208 (January): 758–66. https://doi.org/10.1016/j.envpol.2015.10.056.
Lin, Y-C., and M-T. Cheng. 2007. “Evaluation of Formation Rates of NO2 to Gaseous and Particulate Nitrate in the Urban Atmosphere.” Atmospheric Environment 41 (9): 1903–10. https://doi.org/10.1016/j.atmosenv.2006.10.065.
Lodge, Jr. 1988. Methods of Air Sampling and Analysis. Edited by James P. Lodge. 3rd ed. Boca Raton: CRC Press LLC.
Macintyre, Helen L., Clare Heaviside, Lucy S. Neal, Paul Agnew, John Thornes, and Sotiris Vardoulakis. 2016. “Mortality and Emergency Hospitalizations Associated with Atmospheric Particulate Matter Episodes across the UK in Spring 2014.” Environment International 97 (December): 108–16. https://doi.org/10.1016/j.envint.2016.07.018.
Malik, Amrita, and Roma Tauler. 2015. “Exploring the Interaction between O3 and NOx Pollution Patterns in the Atmosphere of Barcelona, Spain Using the MCR–ALS Method.” Science of The Total Environment 517 (June): 151–61. https://doi.org/10.1016/j.scitotenv.2015.01.105.
Mannucci, Pier Mannuccio, Sergio Harari, Ida Martinelli, and Massimo Franchini. 2015. “Effects on Health of Air Pollution: A Narrative Review.” Internal and Emergency Medicine 10 (6): 657–62. https://doi.org/10.1007/s11739-015-1276-7.
Matsumoto, Mitsuhiro, and Toshiichi Okita. 1998. “Long Term Measurements of Atmospheric Gaseous and Aerosol Species Using an Annular Denuder System in Nara, Japan.” Atmospheric Environment 32 (8): 1419–25. https://doi.org/10.1016/S1352-2310(97)00270-7.
Mozeto, Antonio A. 2001. “Química Atmosférica: A Química Sobre Nossas Cabeças.” Química Nova, no. Edição Especial: 41–49.
Murruni, L.G., V. Solanes, M. Debray, A.J. Kreiner, J. Davidson, M. Davidson, M. Vázquez, and M. Ozafrán. 2009. “Concentrations and Elemental Composition of Particulate Matter in the Buenos Aires Underground System.” Atmospheric Environment 43 (30): 4577–83. https://doi.org/10.1016/j.atmosenv.2009.06.025.
Myers, N, R a Mittermeier, C G Mittermeier, G a da Fonseca, and J Kent. 2000. “Biodiversity Hotspots for Conservation Priorities.” Nature 403 (6772): 853–58. https://doi.org/10.1038/35002501.
Nie, Wei, Tao Wang, Wenxing Wang, Xiaolin Wei, and Qian Liu. 2013. “Atmospheric Concentrations of Particulate Sulfate and Nitrate in Hong Kong during 1995–2008: Impact of Local Emission and Super-Regional Transport.” Atmospheric Environment 76 (September): 43–51. https://doi.org/10.1016/j.atmosenv.2012.07.001.
Pandolfi, Marco, Yolanda Gonzalez-Castanedo, Andrés Alastuey, Jesus D. de la Rosa, Enrique Mantilla, A. Sanchez de la Campa, Xavier Querol, Jorge Pey, Fulvio Amato, and Teresa Moreno. 2011. “Source Apportionment of PM10 and PM2.5 at Multiple Sites in the Strait of Gibraltar by PMF: Impact of Shipping Emissions.” Environmental Science and Pollution Research 18 (2): 260–69. https://doi.org/10.1007/s11356-010-0373-4.
Parmar, R.S, G.S Satsangi, A Lakhani, S.S Srivastava, and S Prakash. 2001. “Simultaneous Measurements of Ammonia and Nitric Acid in Ambient Air at Agra (27°10′N and 78°05′E) (India).” Atmospheric Environment 35 (34): 5979–88. https://doi.org/10.1016/S1352-2310(00)00394-0.
Perrino, C, M Catrambone, A Di Menno Di Bucchianico, and I Allegrini. 2002. “Gaseous Ammonia in the Urban Area of Rome, Italy and Its Relationship with Traffic Emissions.” Atmospheric Environment 36 (34): 5385–94. https://doi.org/10.1016/S1352-2310(02)00469-7.
Pio, C.A., I.M. Santos, T.D. Anacleto, T.V. Nunes, and R.M. Leal. 1991. “Particulate and Gaseous Air Pollutant Levels at the Portuguese West Coast.” Atmospheric Environment. Part A. General Topics 25 (3–4): 669–80. https://doi.org/10.1016/0960-1686(91)90065-F.
Reche, Cristina, M. Viana, T. Moreno, X. Querol, A. Alastuey, J. Pey, M. Pandolfi, et al. 2011. “Peculiarities in Atmospheric Particle Number and Size-Resolved Speciation in an Urban Area in the Western Mediterranean: Results from the DAURE Campaign.” Atmospheric Environment 45 (30): 5282–93. https://doi.org/10.1016/j.atmosenv.2011.06.059.
Reche, Cristina, Mar Viana, Marco Pandolfi, Andrés Alastuey, Teresa Moreno, Fulvio Amato, Anna Ripoll, and Xavier Querol. 2012. “Urban NH3 Levels and Sources in a Mediterranean Environment.” Atmospheric Environment 57 (September): 153–64. https://doi.org/10.1016/j.atmosenv.2012.04.021.
Ritz, Beate, Pei-Chen Lee, Johnni Hansen, Christina Funch Lassen, Matthias Ketzel, Mette Sørensen, and Ole Raaschou-Nielsen. 2016. “Traffic-Related Air Pollution and Parkinson’s Disease in Denmark: A Case–Control Study.” Environmental Health Perspectives 124 (3): 351–56. https://doi.org/10.1289/ehp.1409313.
Schleicher, Nina, Stefan Norra, Fahe Chai, Yizhen Chen, Shulan Wang, and Doris Stüben. 2010. “Anthropogenic versus Geogenic Contribution to Total Suspended Atmospheric Particulate Matter and Its Variations during a Two-Year Sampling Period in Beijing, China.” J. Environ. Monit. 12 (2): 434–41. https://doi.org/10.1039/B914739J.
Scudlark, Joseph R., Jennifer A. Jennings, Megan J. Roadman, Karen B. Savidge, and William J. Ullman. 2005. “Atmospheric Nitrogen Inputs to the Delaware Inland Bays: The Role of Ammonia.” Environmental Pollution 135 (3): 433–43. https://doi.org/10.1016/j.envpol.2004.11.017.
Swaluw, Eric van der, Willem A.H. Asman, Hans van Jaarsveld, and Ronald Hoogerbrugge. 2011. “Wet Deposition of Ammonium, Nitrate and Sulfate in the Netherlands over the Period 1992–2008.” Atmospheric Environment 45 (23): 3819–26. https://doi.org/10.1016/j.atmosenv.2011.04.017.
Ta, Wanquan, Tao Wang, Honglang Xiao, Xueyi Zhu, and Zhen Xiao. 2004. “Gaseous and Particulate Air Pollution in the Lanzhou Valley, China.” Science of The Total Environment 320 (2–3): 163–76. https://doi.org/10.1016/j.scitotenv.2003.08.026.
Tagliatella, Edipo Vinicius dos Santos. 2014. “Avaliação Da Qualidade Do Ar No Colégio Estados Unidos Em Paranaguá-PR.” Matinhos: Universidade Federal do Paraná.
The R Development Core Team. 2008. R: A Language and Environment for Statistical Computing. Vienna, Austria: R Foundation for Statistical Computing.
Tzannatos, Ernestos. 2010. “Ship Emissions and Their Externalities for the Port of Piraeus – Greece.” Atmospheric Environment 44 (3): 400–407. https://doi.org/10.1016/j.atmosenv.2009.10.024.
US EPA. 2015. “Transportation, Air Pollution, and Climate Change.” United States Environmental Protection Agency. 2015. https://www.epa.gov/transportation-air-pollution-and-climate-change.
Viana, Mar, Pieter Hammingh, Augustin Colette, Xavier Querol, Bart Degraeuwe, Ina de Vlieger, and John van Aardenne. 2014. “Impact of Maritime Transport Emissions on Coastal Air Quality in Europe.” Atmospheric Environment 90 (June): 96–105. https://doi.org/10.1016/j.atmosenv.2014.03.046.
Walker, J.T., Dave R Whitall, Wayne Robarge, and Hans W. Paerl. 2004. “Ambient Ammonia and Ammonium Aerosol across a Region of Variable Ammonia Emission Density.” Atmospheric Environment 38 (9): 1235–46. https://doi.org/10.1016/j.atmosenv.2003.11.027.
Weisskopf, Marc G., Marianthi-Anna Kioumourtzoglou, and Andrea L. Roberts. 2015. “Air Pollution and Autism Spectrum Disorders: Causal or Confounded?” Current Environmental Health Reports 2 (4): 430–39. https://doi.org/10.1007/s40572-015-0073-9.
WHO. 2013. “Health Effects of Particulate Matter. Policy Implications for Countries in Eastern Europe, Caucasus and Central Asia (2013).” World Health Organization - WHO. 2013. http://www.euro.who.int/en/health-topics/environment-and-health/air-quality/publications/2013/health-effects-of-particulate-matter.-policy-implications-for-countries-in-eastern-europe,-caucasus-and-central-asia-2013.
———. 2016. “Ambient Air Pollution: A Global Assessment of Exposure and Burden of Disease.” World Health Organization - WHO. 2016. http://www.who.int/phe/publications/air-pollution-globalassessment/en/.
Wu, Yiyun, Baojing Gu, Jan Willem Erisman, Stefan Reis, Yuanyuan Fang, Xuehe Lu, and Xiuming Zhang. 2016. “PM2.5 Pollution Is Substantially Affected by Ammonia Emissions in China.” Environmental Pollution 218 (November): 86–94. https://doi.org/10.1016/j.envpol.2016.08.027.
Yamamoto, Noriko, Hideaki Nishiura, Takahisa Honjo, Yoshiki Ishikawa, and Koji Suzuki. 1995. “A Long-Term Study of Atmospheric Ammonia and Particulate Ammonium Concentrations in Yokohama, Japan.” Atmospheric Environment 29 (1): 97–103. https://doi.org/10.1016/1352-2310(94)00226-B.
Zbieranowski, Antoni L., and Julian Aherne. 2012. “Spatial and Temporal Concentration of Ambient Atmospheric Ammonia in Southern Ontario, Canada.” Atmospheric Environment 62 (December): 441–50. https://doi.org/10.1016/j.atmosenv.2012.08.041.
Zhou, Ying, Shuiyuan Cheng, Dongsheng Chen, Jianlei Lang, Gang Wang, Tingting Xu, Xiaoqi Wang, and Sen Yao. 2015. “Temporal and Spatial Characteristics of Ambient Air Quality in Beijing, China.” Aerosol and Air Quality Research 15 (5): 1868–80. https://doi.org/10.4209/aaqr.2014.11.0306.

Downloads

Publicado

2020-03-04

Como Citar

SOUZA, Felipe Foroni Cota; TAGLIATELA, Edipo Vinicius; GURGATZ, Bruno Martins; HUERGO, Luciano Fernandes; REIS, Rodrigo Arantes. Análise de NO2, NH3 e PTS na Atmosfera de Paranaguá - PR. Fronteira: Journal of Social, Technological and Environmental Science, [S. l.], v. 9, n. 1, p. 212–229, 2020. DOI: 10.21664/2238-8869.2020v9i1.p212-229. Disponível em: https://revistas2.unievangelica.edu.br/index.php/fronteiras/article/view/2938. Acesso em: 26 dez. 2024.